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32213

Sigma-Aldrich

 

Methanol

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.8% (GC)

Synonym:Methyl alcohol
CAS Number:67-56-1
Linear Formula:CH3OH
Molecular Weight:32.04
Beilstein Registry Number:1098229
EC Number:200-659-6
MDL number:MFCD00004595
PubChem Substance ID:24859298

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Description

PackagingIn PE-bottles; also available Glass-bottles (Material no. ending with *-GL)
 6×1, 2.5, 72×2.5 L in glass btl

Properties

gradeACS reagent, reag. ISO, reag. Ph. Eur.
vapor density1.11 (vs air)
vapor pressure410 mmHg ( 50 °C)
 97.68 mmHg ( 20 °C)
 puriss. p.a.
assay≥99.8% (GC)
autoignition temp.725 °F
expl. lim.36 %
total impurities≤0.00005% free alkali (as NH3)
 ≤0.0001% formaldehyde
 ≤0.00025% KMnO4 red. matter (as O)
 ≤0.0005% non-volatile matter
 ≤0.001% acetaldehyde
 ≤0.001% acetone (GC)
 ≤0.05% water (Karl Fischer)
 ≤0.1% ethanol (GC)
refractive indexn20/D 1.329(lit.)
bp64.7 °C(lit.)
mp−98 °C(lit.)
density0.791 g/mL at 25 °C(lit.)
anion traceschloride (Cl-): ≤0.5 mg/kg
 sulfate (SO42-): ≤1 mg/kg
cation tracesAl: ≤0.5 mg/kg
 B: ≤0.02 mg/kg
 Ba: ≤0.1 mg/kg
 Bi: ≤0.1 mg/kg
 Ca: ≤0.5 mg/kg
 Cd: ≤0.05 mg/kg
 Co: ≤0.02 mg/kg
 Cr: ≤0.02 mg/kg
 Cu: ≤0.01 mg/kg
 Fe: ≤0.1 mg/kg
 Li: ≤0.1 mg/kg
 Mg: ≤0.1 mg/kg
 Mn: ≤0.01 mg/kg
 Mo: ≤0.1 mg/kg
 Na: ≤0.5 mg/kg
 Ni: ≤0.02 mg/kg
 Pb: ≤0.02 mg/kg
 Sn: ≤0.1 mg/kg
 Sr: ≤0.1 mg/kg
 Zn: ≤0.1 mg/kg

Safety

Personal Protective EquipmentEyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
Hazard CodesF,T
Risk Statements11-23/24/25-39/23/24/25
Safety Statements7-16-36/37-45
RIDADRUN1230 3/PG 2
WGK Germany1
RTECSPC1400000
UEL36.00%(V)
LEL6.00%(V)
Flash Point(F)51.8 °F
Flash Point(C)11 °C

References

MerckMerck 13,5984
BeilsteinBeil. 1,IV,1227
referenceAldrich MSDS 1, 1202:C / Corp MSDS 1 (2), 2281:C / FT-IR 2 (1), 160:B / FT-IR 1 (1), 109:B / FT-NMR 1 (1), 163:A / IR-Spectra (3), 66:A / IR-Spectra (2), 64:A / NMR-Reference 2 (1), 101:A / RegBook 1 (1), 121:A / Sax 6, 1764 / Sigma FT-IR 1 (1), 1344:A / Structure Index 1, 14:A:1 / Vapor Phase 3, 155:B